
By Gribble Gordon W. and Joule John A. (Eds.)
ISBN-10: 0080444822
ISBN-13: 9780080444826
This can be the 16th annual quantity of development in Heterocyclic Chemistry, and covers the literature released in the course of 2003 on many of the very important heterocyclic ring systems.This quantity opens with really expert reports. the 1st covers 'Lamellarins: Isolation, task and synthesis' an important crew of biologically lively marine alkaloids and the second one discusses 'Radical Additions to Pyridines, Quinolines and Isoquinolines'. the rest chapters research the new literature at the universal heterocycles so as of accelerating ring measurement and the heteroatoms current.
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Additional info for A critical review of the 2003 literature preceded by two chapters on current heterocyclic topics
Example text
Samarium(II) iodide also gave the reaction, albeit in reduced yield (Scheme 44). I Bu3SnH, AIBN 9 see below PhMe, 80 ~ ~ X \--N ~ 157, X = I 158, X = Br 156, 97% 159 Bu3SnH, AIBN, PhMe, 80 ~ (Me3Si)3SiH, AIBN, PhMe, 80 ~ Bu3GeH, AIBN, PhMe, 80 ~ Sml2, THF, HMPA, RT hv, MeCN, Quartz cell, RT (Bu3Sn)2, by, MeCN, Quartzcell, RT 98% 99% 97% 75% 23% 24% Scheme 44 'Catalytic' tributyltin hydride methodologies were also studied, with sodium borohydride used as a co-reductant <03OBC4047>. In all cases examined, the yield for cyclisation of 157 to 159 was reduced substantially.
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A critical review of the 2003 literature preceded by two chapters on current heterocyclic topics by Gribble Gordon W. and Joule John A. (Eds.)
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